Customization: | Available |
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CAS No.: | 108-05-4 |
Formula: | C4h6o2 |
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Certificate of Analysis | |||
Commodity | Vinyl Acetate | Standard | SH/T 1628.1-2016 |
Batch number | |||
Items | Index | Result | |
Superior | |||
Appearance | Colorless and transparent liquid, no mechanical impurity | Transparent, free of impurities | |
Density(20ºC)/(g/cm3) | 0.930-0.934 | 0.9323 | |
Purity,% ≥ | 99.8 | 99.95 | |
Chromaticity (in Hazen) (Pt-Co),≤ | 5 | 5 | |
Aldehyde(as acetaldehyde)/(mg/kg)≤ | 200 | 56 | |
Moisture/(mg/kg)≤ | 400 | 250 | |
Acidity(as acetic acid)/(mg/kg)≤ | 40 | 40 | |
Evaporites/(mg/kg) | 50 | / | |
Methyl acetate/(mg/kg) | 63 | ||
Ethyl acetate/(mg/kg) | 12 | ||
Benzene/(mg/kg) ≤ | 20 | 19 | |
Activity degree/min | 11 | ||
Polymerization inhibitor(Hydroquinone) | |||
Test Conclusion | |||
Remark | 1,4-Benzoquinone: 6.7ppm |
1.Polymerization:
It can be polymerized to give polyvinylacetate. With other monomers can be used to prepare copolymerssuch as ethylene-vinyl acetate (EVA), vinylacetate-acrylic acid (VA/AA), polyvinyl chloride acetate (PVCA), and polyvinylpyrrolidone (Vp/Va Copolymer, used in hair gels).Due to the instability of the radical, attempts to control the polymerizationvia most 'living/controlled' radical processes have proved problematic.However, RAFT (or more specifically MADIX)polymerization offers a convenient method of controlling the synthesis of PVAby the addition of a xanthate or a dithiocarbamate chain transfer agent.
2.Other reactions:
Vinyl acetate undergoes many of the reactions anticipated for an alkeneand an ester.Bromineadds to give the dibromide. Hydrogen halides add to give 1-haloethyl acetates,which cannot be generated by other methods because of the non-availability ofthe corresponding halo-alcohols. Acetic acid adds in the presence of palladiumcatalysts to give ethylidene diacetate, CH3CH(OAc)2. Itundergoes transesterification with a variety of carboxylicacids.The alkene also undergoes Diels-Alderand 2+2 cycloadditions.
3.Toxicity evaluation:
On January 31, 2009, the Government of Canada's final assessment concludedthat exposure to vinyl acetate is not considered to be harmful to human health.Thisdecision under the Canadian Environmental Protection Act (CEPA) was based onnew information received during the public comment period, as well as morerecent information from the risk assessment conducted by the European Union.
Notice
May contact its vapor, should wear self-suction filter type gas mask (half mask) emergency rescue or evacuation, it is recommended to wear air breathing
Wear protective chemical safety glasses,Wear antistatic work clothes
Do not smoke after work, shower and change clothes, pay special attention to eye and respiratory protection
Certification
Packing & Shipping
180kg/drum, 80drum/20ft container=14.4mts/20ft container
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